Lithium Recovery From Lapindo Sludge Water (Brine) By Adsorption Method Using Manganese Dioxide (Mno2) Adsorbent
DOI:
https://doi.org/10.59188/eduvest.v5i2.3774Keywords:
Lithium, Adsorption, Manganese Dioxide, Lapindo, Recovery, FreundlichAbstract
This article discusses the recovery of lithium from Lapindo sludge water in Sidoarjo using the adsorption method with Manganese Dioxide (MnO2) adsorbents. This study aims to determine the optimal lithium recovery rate based on variations in stirrer speed and adsorbent concentration. The results of the analysis showed that the stirring speed of 150 rpm with an adsorbent concentration of 2.5 g/L gave the highest lithium recovery result, which was 53.2 ppm. In addition, the adsorption process follows the Freundlich model, showing that the adsorbent has a good capacity to bind lithium from the solution. This research provides new insights into the use of sludge water as an alternative source of lithium in Indonesia.
References
Ciez, RE dan Whitacre, JF. 2016, ‘The Cost of Lithium is Unlikely to Upend The Price of Li-Ion Storage Systems’, Journal of Power Sources, vol. 3, no.3, hh. 310-313. https://doi.org/10.1016/j.jpowsour.2016.04.073
Handayani, Murni dan S., Eko 2012, ‘Uji Persamaan Langmuir dan Freundlich pada Penyerapan Limbah Chrom (VI) Oleh Zeolit’, Jurnal Prosiding Seminar Nasional Sains dan Teknologi Nuklir, vol. 1, no. 3, hh. 130-136. https://www.researchgate.net/publication/295072492_UJI_PERSAMAAN_LANGMUIR_DAN_FREUNDLICH_PADA_PENYERAPAN_LIMBAH_CHROM_VI_OLEH_ZEOLIT
Huang, M., Li, F., Dong, F., Zhang, Y.X. and Zhang, L.L. 2015, ‘MnO2-Based Nanostructures For High-Performance Supercapacitors’, Journal of Materials Chemistry A, vol. 3, no. 43, hh. 21380-21423. https://doi.org/10.1039/C5TA05523G
Iftekhar, S., Ramasamy, D.L., Srivastava, V., Asif, M.B. and Sillanpää, M. 2018, ‘Understanding The Factors Affecting The Adsorption of Lanthanum Using Different Adsorbents: A Critical Review’, Chemosphere Journal, vol. 204, hh.413-430. https://doi.org/10.1016/j.chemosphere.2018.04.053
Juniawan, A., Rumhayati, B dan Ismuyanto, B. 2013. ‘Karakteristik Lumpur Lapindo dan Fluktuasi Logam Berat Pb dan Cu pada Sungai Porong dan Aloo’, Jurnal Sains dan Terapan Kimia, vol. 7, no. 1, hh. 50-59. http://dx.doi.org/10.20527/jstk.v7i1.2120
Kim, N., Su, X. and Kim, C. 2020, ‘Electrochemical Lithium Recovery System Through The Simultaneous Lithium Enrichment Via Sustainable Redox Reaction’, Chemical Engineering Journal, hh.127715. https://doi.org/10.1016/j.cej.2020.127715
Krebs, R.E. 2006, The History And Use Of Our Earth's Chemical Elements: A Reference Guide, Greenwood Publishing Group, New York.
Manao, R.D., Alfianto, R. dan Sumarno, S. 2012, ‘Recovery Garam Lithium Pada Air Tua (Bittern) dengan Metode Presipitasi’, Jurnal Teknologi Kimia dan Industri, vol. 1, no. 1, hh.292-297. http://103.28.220.26/index.php?ref=browse&mod=viewarticle&article=73162
Masruhin, M., Rasyid, R. dan Yani, S. 2018, ‘Penjerapan Logam Berat Timbal (Pb) dengan Menggunakan Lignin Hasil Isolasi Jerami Padi’, Journal of Chemical Process Engineering, vol. 3, no. 1, hh.11-20. https://doi.org/10.33536/jcpe.v3i1.189
Natasha, N.C., Lalasari, L.H., Rohmah, M. dan Sudarsono, J.W. 2018, ‘Ekstraksi Lithium dari β–Spodumen Hasil Dekomposisi Batuan Sekismika Indonesia Menggunakan Aditif Natrium Sulfat’, Jurnal Metalurgi, vol. 33, no. 2, hh.69-78. http://dx.doi.org/10.14203/metalurgi.v33i2.429
Nurafriyanti., Prihatini, N.S. dan Syauqiah, I. 2017, ‘Pengaruh Variasi pH dan Berat Adsorben dalam Pengurangan Konsentrasi Cr Total pada Limbah Artifisial Menggunakan Adsorben Ampas Daun Teh’, Jurnal Teknik Lingkungan, vol. 3, no. 1, hh. 56-65. http://dx.doi.org/10.20527/jukung.v3i1.3200
Prianjani, D dkk. 2016, ‘The Standard Development for the National Standard of Indonesian (SNI) of the Cell Traction Battery Lithium-ion Ferro Phospate Secondarry for Electric Vehicles Applications’, 2nd International Conference of Industrial, Mechanical, Electrical, Chemical Engineering (ICIMECE), vol. 3, no. 3, hh 213-218. 10.1109/ICIMECE.2016.7910460
Recky, Pattiasina J. 2020, Pengendalian Lumpur Sidoarjo, Direktorat Jendral Sumber Daya Air Pusat Pengendalian Lumpur, Sidoarjo.
Salafudin. 2021. ‘Sumberdaya Alam Lithium Indonesia’, Jurnal Teknologi Ramah Lingkungan, vol. 5, no. 2, hh. 178-187. https://doi.org/10.26760/jrh.v5i2.178-187
Samudro, G., Hadiwidodo, M. dan Aji, F. 2016, ‘Penentuan Campuran Lumpur Lapindo sebagai Substitusi Pasir dan Semen dalam Pembuatan Paving Block Ramah Lingkungan’, Jurnal Presipitasi, vol. 13, no. 1, hh 13-20. https://doi.org/10.14710/presipitasi.v13i1.13-20
Sapputra, G.P.A dan Noerochim, L. 2014, ‘Pengaruh Waktu Hidrotermal pada Proses Sintesis Lithium Mangan Oksida Spinel (LiMn2O4) Nanopartikel terhadap Efisiensi Adsorpsi dan Desorpsi Ion Lithium dari Lumpur Sidoarjo’, Jurnal Teknik Pomits, vol. 3, no. 2, hh. 163-167. 10.12962/j23373539.v3i2.6601
Siregar, M.Y. 2019, ‘Model Isoterm Adsorpsi Lithium Dari Brine Water, Bogor Menggunakan Adsorben Hydrous Manganese Oxide (HMO) dengan Variasi Dosis Adsorben dan Waktu Adsorpsi’, Jurnal Metalurgi, vol. 34, no. 3. http://dx.doi.org/10.14203/metalurgi.v34i3.478
Sumarno, S., Ratnawati, R. dan Nugroho, A.N.A. 2012, ‘Recovery Garam Lithium dari Air Asin (Brine) dengan Metoda Presipitasi’, Jurnal Teknik, vol. 33, no. 2, hh.67-69. https://doi.org/10.14710/teknik.v33i2.4387
Suprapto, S.J., Gunradi, R dan Ramli, Y.R. 2012, ‘Geokimia Sebaran Unsur Logam pada Endapan Lumpur Sidoarjo’, Jurnal Geokimia, vol. 1, no. 1, hh. 1-9. https://doi.org/10.47599/bsdg.v2i2.209
Syauqiah, I., Amalia, M. dan Kartini, H.A. 2011, ‘Analisis Variasi Waktu dan Kecepatan Pengaduk Pada Proses Adsorpsi Limbah Logam Berat dengan Arang Aktif’, Jurnal Infoteknik, vol. 12, no. 1, hh.11-20.
http://dx.doi.org/10.20527/infotek.v12i1.1773
Udyani, K. 2010, ‘Adsorpsi Deterjen dalam Air Menggunakan Adsorben Karbon Aktif pada Kolom Fluidisasi’, Jurnal ITATS, hh.1-6. https://scholar.google.com/scholar?oi=bibs&cluster=568381284431347448&btnI=1&hl=en
Widayatno, T. 2017, ‘Adsorpsi Logam Berat (Pb) Dari Limbah Cair Dengan Adsorben Arang Bambu Aktif’, Jurnal Teknologi Bahan Alam, vol. 1, no. 1, hh.17-23. http://dx.doi.org/10.22487/j24775185.2016.v5.i2.8002.
Downloads
Additional Files
Published
How to Cite
Issue
Section
License
Copyright (c) 2025 Adinda Nurkholisha, R.A. Elisa Eka Purnamasari

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.